This study examines the relationship between corporate sustainability practices and the likelihood of incurring environmental penalties, focusing on S&P 500 firms from 2000 to 2024. As global pressure mounts for businesses to adopt sustainable practices due to stakeholder expectations and stringent regulations, companies face increasing risks of environmental noncompliance. Although environmental penalties serve as a deterrent, limited research has explored whether sustainability practices can predict a firm’s likelihood of receiving penalties. This study addresses this gap by analyzing the predictive role of corporate characteristics, including ESG performance, environmental scores, and governance practices, in assessing penalty risks. Utilizing ESG data from Refinitiv and penalty records from the Violation Tracker database, we employ regression analysis to determine whether high ESG scores and robust governance frameworks correlate with reduced penalty risks, indicating enhanced risk management and regulatory adherence. Our findings offer actionable insights into aligning corporate sustainability with regulatory standards and mitigating environmental risks.